Chemistry
Nickel–cadmium accumulator
The nickel–cadmium accumulator is very common. Its electromotive force is E= 1.3 V.
The electrolyte is an aqueous potassium hydroxide solution
(potash),containing: ( ), ( )
During discharge, the reactions occurring at the electrodes correspond to the forward direction of
the following equations:
NiO(OH)(s) + H O(l) + e → Ni(OH) (s) + OH (aq)
Cd(s) + 2 OH (aq) → Cd(OH) (s) + 2 e
1. What is the positive terminal of this battery?
2. a) What redox couples are involved in this accumulator?
b) Write the overall operating (discharge) reaction of a nickel–cadmium battery.
c) What is the role of NiO(OH)(s)the nickel oxyhydroxide electrode?
3.
a) To which electrode must the positive terminal of a DC voltage source be connected to
recharge this accumulator?
b) Give the equation of the reaction corresponding to the charging of the accumulator.
4. The accumulator is recharged using a constant current = 2.0 A for 40 min.
a) Calculate the total electric charge delivered to the accumulator.
b) Calculate the mass of he nickel oxyhydroxide NiO(OH)formed during the charging
process.
Data: = 9.65 × 10 C mol ,(Ni) = 58.7 g mol ,
(O) = 16.0 g mol ,(H) = 1.0 g mol )