THE LEAD-ZINC-BEARING PAUL DEPOSITS OF TUNISIA SAINFELD CONTENTS PAGE Abstract .............................................................. Introduction .......................................................... 150 150 Geographic distribution of principal deposits ............................ History .............................................................. Discovery and exploitation .......................................... Evolution of theories of ore genesis .................................. Geologic background .................................................. 151 151 151 154 158 Tectonic frame ..................................................... Tectonic units ................................................... Structural features .............................................. Problem of the Triassic .......................................... 158 158 160 161 Stratigraphic distribution ........................................... Character of deposits .................................................. Types of deposits................................................... 161 165 165 Oxidation ......................................................... Tectonic distribution ................................................ Character of ores ................................................... 169 169 170 Major elements ................................................. 170 Minor 171 elements ................................................. Gangue and accessoryminerals ................................... Origin of the hydrothermalsolutions.................................. Age of mineralization ............................................... Conclusions:Conditionsof deposition.................................... 172 172 174 174 References 176 ........................................................... ABSTRACT Metalliferous depositsconstitute an important factor in the economy of Tunis. Iron-lead-zinc mineralization is representedby small scattered depositsthroughout the northwesternhalf of the country. The deposits are telethermaland related to the end of Alpine orogeny, Mio-Pliocene in age. A convenient classificationis afforded by the structural framework; they are along great northeast-southwest strike faults. The formations most favorable to mineralization are the Miocene (calcareous and sandyto conglomeratic),the Senonian,the Aptian, the Jurassiclimestones, and the marginal brecciasof the Triassic. INTRODUCTION EXTRACTION of mineral productshasbeena major elementin the Tunisian economy thepast80 years. Mineralproduction, in thousands of tons,for the wholemodernperiodup to January1954is givenin Table 1. 150 THE LEAD-ZINC-BEARING DEPOSITS OF TUNISIA TABLE Products I Marketable tonnage (In thousands of metric tons) Phosphates of lime ................ 151 Metal tonnage (In thousands of metric tons) 79,365 12,067 Iron ............................. Lead ............................ Zinc ............................. 782 315 Lignite .......................... Pyrite ........................... Manganese ....................... Copper .......................... Mercury ......................... 972 15 24 5 9 2 0.02 Strontium ........................ Fluorite .......................... Barite ........................... 2.5 12 3 In market value, nearly 30 percent of the mean annual productionis at presentrepresentedby lead and zinc. GEOGRAPHIC DISTRIBUTION OF PRINCIPAL DEPOSITS The metalliferousdepositsin Tunisia are locatedalmost exclusivelyin the stronglyfoldedrocksthat occupythe northernpart of the country,i.e., betweenthe 35thand37thparallels,approximately in a square200 kilometers on a side. The only exceptionsare somesmall indicationsof lead-zincand manganese and mostof the great sedimentarydeposits(iron and phosphates) of central Tunisia. The principal depositsof the iron-lead-zincassociationare found, therefore, in the richestand most temperatepart of Tunisia, but also in the difficultmountainous regions. In this countrywhere the maximumaltitude is at 1,544,many depositsare at an elevationabove1,000 m. Nevertheless, the generaltopographypresentsa seriesof depressions in a NE-SW direction, traversedby the great routesof communication;the distanceto the shipping port (Tunis) from the mostdistantmine doesnot exceed300 km. The railroad systemservesthe principal mines, but the most out of the way are forty km from a loading station. The mineralmap of Tunisia showsthe scattereddistributionof the hydrothermaldeposits. In the northernregion,amongthe hundredsof showings, aboutsixty ore depositshavebeenor are in production. Only a scorecanbe consideredas small mining districts with a total productionof more than 10,000tonsof metaland,amongthese,threeare really important(more than 100,000tonsof metal). The districtsare not distributedevenlyin the region; most of them are groupedin the roughestzone, that is to say in the northwesternportionof the square,with a rather uniform distribution,at most fifty km apart. HISTORY Discovery and Exploitation The first Europeanprospectors in Tunisia in the last quarterof the 19th century were guidedby the old workingsthat marked most of the outcrops 152 PAUL S,4INFELD Map of mine areas inTUNISIA ,• • FIG. 1. THE LEAD-ZINC-BEARING DEPOSITS OF TUNIS'IA 153 Of ore. Certainlead ore deposits,in particular,had dumpsand important mineworkings(Djebel Ressas,Sidi Amor ben Salem,Bou Jaber,Khanguet). These remainsare generallyconsideredRoman by our modernminers; but somehistorians,like St. Gsell (21), think that "the most active epochfor the mining industry in Barbary was the middle ages and not antiquity." Howeverdocuments are scarce;inscriptions tell little and there is no indication that the North African mineral resourceswere utilized by the Carthaginians, or evenat the beginningof the Romandomination. The first written recordsdatefrom the Christianera: texts datingfrom the 2nd to the 5th centuriesmakementionof sentenceto forcedlabor in mines;on the other hand,someof the mineworkers'tools (like oil lamps), foundin the mines, have been dated 2nd and 3rd centuries. It is probablethat the Arab invasion,in the 7th century,causeda temporary cessation of mining and it was not until the 9th century,that references are foundin the Arab literature. With respectto Tunisia, all the texts from the 9th to the 14thcenturies,mentiononly the minesof Mejjana ("Majjanael-Ma'adin")--referring to a district locatedon the Algerian-Tunisianfrontier, to the north of Tebessa,which may have includedthe minesof Mesloula, Ouenza,Bou Khadra, Slata andBou Jaber. The latter place,whereextensive mine dumpshave been found, may have been a center for ore treatment. Another referenceis in the accountof the journey of Flamand Adome, who notedthe activityof the lead mineof Djebel Ressasin June 1470. It appearsthat mining diminishedgreatly in the 16th century,when the Europeansbeganto importarticlesof metaland leadto North Africa. There are no further recordsuntil the modern period except in the 18th century, in theaccounts by Pessonel(1724) andby Hebenstreit(1732), who described the mine of Khanguet,and alsoin the accountby the EnglishmanShaw, who tellsof Djebel Ressas;this is the localitythat yieldedthe Arab relics (lamps and pottery). In the 19th century,upon the arrival of the French in North Africa, no mineswere in operation. Until the treaty of Kassar-Said(1881) only two concessions had beengrantedin Tunisia by the Kheredinegovernment:the Djebel Ressasin 1869 and Djebba, in 1874. Nearly all the mineraldepositswere discovered during the modernperiod, in the courseof the initial phaseof researchand exploration,from 1880 to 1905. The development phase,from 1894 to 1914, was characterized by an almostcontinuous increasein production(with a maximumof 37,400tonsof zinc ores in 1912, and 59,500 tons of lead ores in 1913). Then the war and fall in pricesbroughton the first productioncrisisfrom 1914 to 1922, and many mineswere abandonedduring this period. A notableresumptionaccompanied the rise in prices. Productionincreasedfrom 1922 to 1930, with a maximum of 40,000 tons of lead ore in 1924, and 30,000 of zinc ore in 1926. The Tunisianmineswere at that time stronglyaffectedby the depreciation of zinc prices,and next by the world economiccrisis,whichbroughtaboutan almostcompletestoppage,from 1930to 1936. A new impulse,startingfrom 154 PAUL SAINFELD TABLE PRODUCTION' II OF PRINCIPAL MIN.•-S (Estimated in tons of metal) Total production to January 1st, 1954 Name Maximum annual production Production for 1953 of mine Lead Djebel Ressas 63,600 Sidi Amor ben Salem Lead Zinc 63,650 4,902 2,097 108,800 Djebel Hallour Sidi bou Aouane Khanguet Kef Tout Sakiet Sidi Youssef E1 Grefa Djebel Trozza Garn Alfaya-Koudiat Zinc el 90,700 72,800 34,700 34,800 56,000 51,000 37,800 5,277 120 38,000 27,700 3,217 3,600 292 1,362 3,950 4,338 6,300 2,819 26,200 505 4,357 2,867 Year Lead 1902 800 1924 1,900 1934 1953 1900 1912 1951 1916 1916 Zinc 1,080 2,300 3,600 370 1,500 3,900 1,390 700 Hamra Sidi Ahmed 10,400 Bazina 34,000 Bou Jaber Fedj el Adourn Djebel ben Amara Ain Allega 24,400 16,200 100 13,300 7,000 13,000 24,000 9.400 2,895 348 Ressas-Touireuf Zaghouan 20,800 1,100 700 16,800 2,000 Djebba 11,700 3,750 Oued Maden 15,200 Djebel Semene 12.200 Diebel el Akhouat Djebel Lorbeus Sidi et Tara 3.800 1.300 10.800 1,653 2,150 1,821 840 1912 130 1,743 3,581 1,753 1,964 76 1,457 4.400 7,600 10,000 400 65 620 1898 1,500 1.613 1912 1909 1905 1912 1953 1895 1909 210 400 2,000 120 1941 1,200 1953 4.400 1953 1920 400 1930 230 1.500 1933, was checkedby the secondworld war and by the campaignin Tunisia. Recoverybeganduring 1944and the productionfor the year 1953 surpassed the prewar level. The graphs (Fig. 2) showthe importanceof the TunisianmetaI production in the North African economy. At the first of January,1954,the probable tonnageof metal in reserveswas on the order of 160,000tons of lead and 60,000 of zinc. Evolution of Theories of Ore Genesis As early as 1852, Ville and Coquandobserved,in Algeria, the relation betweenthe lead-zinc-bearingbeds and the Triassic formations,particularly the ophitesthat they contain. Peron stated,in 1883 (32), "It is to the eruption of these spilites,or rather to the plutonic phenomenawhich accompanied it, that is owed the remarkablepresenceof these depositsof minerals, iron, lead, and copperin the midst of the upper beds of the Miocene series." On his trip in 1894,Levat was impressedby the depositsof zinc and the "eruptive gypsums,"associatedwith ophites, in Algeria as well as in Tunisia (30). But the Triassic was identifiedas suchby Marcel Bertrand, at the time THœ Lœ.4D-ZINC-Bœ.4RING DœPO$IT$ OF TUNISL4 155 of the specialsessionof the GeologicalSocietyof France, in Algiers in 1896 and this identificationwas soonextendedto Tunisia by Pervinquiere(33), who stated,"... The frequentrelationbetweenthe Triassicand the calamine deposits. . . one conceives,indeedit follows,that the faults which usually borderthe Trias in this region have given passageto waterschargedwith mineralizers." L TUNISIAN PLUMBO -ZINCIFEROUS PRODUCTION Thou,sar•d.• ort0., '• Tunisian (in market,able ores) , , 1900 retailed ' f9fO , ,•.... • .•.-.•,--' , f9aO Produc[;on t930 COMPARATIVE o½1953 •oYA three TOTAL PRODUCTION countries o• North on January •st,1954 LEAD colourless. f950 •n thousandsoF metal-tons) o• the Lead: f9•O Zinc: hatches with approximative •igures (in hundredsoF metal-tons) Fzc. 2. ZINC A•rica 156 PAUL oeAINFELD However, Pierre Termier, then advisor to several mining companies refusedto admit these faults and in 1895 explainedthis triasificationor "maladiedu Trias": "... the Tunisian zinc oreshad as their original source the Triassicrocksthat musthaveincludeda stratumof sedimentaryzincblende emplacedas an overthrustnappe. This Triassicwas uncoveredand reworked by erosionat a recentperiod; the blendewould thereforehave been dissolved, and reprecipitatedin the form of calamine at limestonecontactsin rocks of all ages." This theorywas recalled,in 1913,by Louis de Launey,who added, however, that one could "explain the formation of the same ores by the actionof hydrothermalcirculationalongthe linesof fracturecorresponding to the boundariesof Triassicblocks"(29). Accordingto J. Berthier (2), all the Tunisian metalliferousdepositsare dueto the Triassic;this stratumwasmineralizedby sulfides,at the periodof its formation,or shortlythereafterand gaveup a part of its mineralizationto the adjacent formationsby the action of circulating waters that have penetrated throughthe upper part in many placesby reasonof the inclinationof the Triassic and the recumbentfolds (2). In 1918,A. Brivespostulated that an intensemineralization, resultingfrom the destructionof an old Hercynianmountainchain,had accumulated at the centerof depressions andTriassiclagoons;the veinlikedepositsresultedfrom the tectonicdraggingout of the deepestTriassicdeposits;the impregnation depositsand replacements resultedfrom the reaction,on the adjacentbeds, of the watersthat had circulatedin the Trias; finally the sedimentarydeposits resultedfrom the erosionof thesesameTriassic deposits(8). L. Berthon (3), who gavea detaileddescriptionof the Tunisianmineral depositsin 1932,considered that "the persistence of strict relationsof proximity so plainly shownbetweenthe Triassicsediments, of which the bulk remainsbarren, and the great majority of developedmetalliferousdeposits, appearas a geodynamic ratherthana geneticphenomenon. It is the great faults and fracturessubsequentto the formation of the Trias that have channelled the hydrothermal circulations, chargedwith metallicfluids,and produced thealteration of thecontact zoneson theborderof theTriassic,the metalliferousincrustationsof the fractures,and the replacementof certain stratafavorableto percolationby water" (3). In a supplement to histhesis(1927) M. Solignac(41) recalledtheseideas and admitted that most of the Tunisian depositsare the "abnormalcontact depositsand the fissureveinsbranchingfrom them.... It is undeniable that the maximumof mineralizationis observedin the regionswhere the great lowerTriassicnappeis bestdeveloped .... This mineralization thinsout in proportionasthe nappebecomeautochthonous.In the southwherethe great tangentialphenomena are almostabsentthe large depositsof lead and zinc ßores do not occur" (41). However,L. Joleaud(25) pointedout in 1929that manyTunisiandeposits are related to fractures in Miocene strata situated far from the Trias. In 1932,he pointedout the role of the Atlas tectonic;"the mineralization,a phenomenonquite late in the Pyrenco-alpinetangentialaction,was here particu- THE LEAD-ZINC-BEARING DEPOSITS OF TUNLS'IA 157 larly activelaterally(that is to sayin its geographic form) and alsovertically (i.e., by reasonof its manifestations of localandregionalintensity)"(27). In 1932-1933,E. Bruet (9) attemptedto provethat the accumulation of the upperportionof the depositswasdueto a supergene phasemainlychemical, followinga hypogenephasehydrothermalor otherwiseand that it had beenfavored,in Tunisia,by climaticinfiuence.s (9, 10, 11). As a result of his examinationof the world distributionof lead-zincdeposits,F. Blondel (5) pointedout that the occurrencein North Africa is entirely in the upper part of the Mesozoic:"Everything takes place as thoughoriginatingat the level of the Paleozoic the zinc and lead mineralization becomesdispersed, scatteringprogressively as it risesin the youngerzones"(5). At the sameperiod, L. Glangeaudsuggesteda more or less remote relation betweenthe ore depositsof northernAlgeria and the eruptiverocks, and proposedthe followingexplanationfor the depositsin relation to the Triassic: "The mineralizationcould have taken place at either one of two periods. In the depositswhich I shall call the primitive, the ore was depositedat thetimeof the intrusionof the eruptiverocks,eitherat their contacts directly in the Triassic, or within the Lias, by fumerolic or hydrothermal action. In what I shallcall emigrantdeposits,the mineralizationdue to eruptive intrusions,was originallylocalizedin the Triassicgypso-saline complex, then it was subsequently distributed,followingthe uplift of the Trias, in the diapir folds and by meansof the circulatingwater taking up the chemical elementsof the Trias" (15). However,L. Calembert(12) thoughtthat therewas generallytoo much deferenceto the aberrantrole of the Triassicand showedthe importanceof the part playedby the lenticularcalcareous formationsin the localizationof certainore deposits. Followinga tour of North Africa in 1949, J. Bouladon (7) presented a synthesis on the leadand zinc depositsas a wholein which he showedthe geographicdistributionof the mineralizedregions,plating the "lead pole" at Oujda, in northernMorocco,with three satellites(to the east,Midelt in centralMorocco,to the west, Beja-Mateur and the AlgerianTunisianfrontier); he alsogavea classification of the typesof deposits and attemptedto establisha correlationbetweentheseand the texture of the ores and also their tenor in minor elements. Finally, in 1951,followingtheir detailedwork on the depositsand the B.P.G. (blende-pyrite-galena) ore of the Teboursouk region,J. Bolzeand Schneiderh/3hn (6) demonstrated the doublerole, tectonicand chemical,of the Triassic,and appliedto theseTunisiandepositsthe idea developed by the Germanmetallogenist in 1941on "secondary hydrothermaldeposits"in zones of active dislocation. "The fractured zone at the contact of the Triassic, with its lode walls, formed at the beginningof the Tertiary, gave an easy passage to externalwaters.... Thesehot salinewaterseasilydissolvedand carried away the sulfidesof the mineralizationsof the basement. The secondary depositionin the overlyingseriesis naturally accomplished after the finalemergence of the regionandthe lastorogenicphase,in the samechannels of circulationat the edgeof the diapirs." 158 PAUL SAINFELD GEOLOGIC BACKGROUND Tunisia is essentiallya sedimentaryterrain; the section, including Mesozoic,Tertiary and Quaternary deposits,is very thick. Only in the north are there outcropsof intrusiverocks. These do not seemto be related to the metalliferousdeposits,whichare all situatedin the sedimentaryformations, with the exceptionof the iron-copperindicationsof the Galite and Nefza. There are, in Tunisia,the classictypesof replacementdepositsand veins, but their distributionis hardly ever sharplydistinguished.Generallythere is no preponderance of oneor of the other,but a type havingmixed characteristics;on onehandveinswith filling of the adjoininginterstices,on the other handimperfectlydevelopedreplacement.Anotherlesscommontype is quite widespreadin Tunida--the so-calledfissure impregnationdeposit, which, moreoveris itself associated with other types of deposition. It is therefore quite difficultto classifythe Tunisian depositsaccordingto their type, but examinationof the tectonicframe providesa simpleclassification, which, in a certain measuredoes not exclude the convergenceof certain dominant characteristics of the deposits. The TunisianDepositsin Relation to the North ,41•ricanTectonicFramework Tunisia represents only the extremeeasternpart of French North Africa at the borderof the Alpine Zone,.and cannotnaturally,be regardedas part of the Algerian Moroccanstructures. TectonicUnits.--Writers have definedthe followingtectoniczones,from North to South (13, 14): MOROCCO ALGERIA TUNISIA -- I Rn* DORSAL KABYLYE-EDOUGH TELLIAN II MOYElq IV ATLAS GALITE KROUMIRIE-NEFzA and BORDER ATLAS HIGH III THE PLATEAUS •BEJAOU TUNISIAN Northwestern-•OU•GH•, ISV•CLINORIma HIGH ATLAS S•H•AN ATLAS . ATLAS rAN'TICLIIqORIUM SoutheasterndCENTRAL1 EASTERN TUNIS I.SoUraERN V A•rr•-ATLAS and SAHARA SAHARAIq PLATFORM TUmS THE LEAD-ZINC-BEARING DEPOSITS OF TUNISIA 159 In Algeria, the structureis superimposed on the paleogeography.Between zonesI and II is the Tellian trench, which correspondsto the subRifaine trench in Morocco,and the Tunisian trench to the east. But on this latter unit, in Tunis, are superimposed the great obliquetectoniclines,which have giventhe countryits presentaspect. In effect,the foldsthat trend eastwestin Algeria,swingto the northeastin the vidnity of the Tunisianfrontier. Their flanks are generally asymmetrical,overturned toward the southeast, representingthrustingfrom the north againstthe central horst, evidentsince the Aptian. This definitivestructureof Tunisia, outlined in a pre-Burdigalianstage, was emphasizedby folds later than early Quaternary. The mineralization appearsrelated to this last manifestationof Alpine orogenesis,and as the depositsare alignedin the northeast-southwest folds,it is proposedto classify themhereaccordingto tectonicunits. Theseare, proceedingfrom the northwest to the southeast: -The Zone of CrystallineMassi.fs,represented in Tunisia only by the small archipelagoof the Galite, is formed by the tertiary eruptiverocks (granodioritesand microgranites),with a more or less metamorphosed Oligocene cover. Only somesmall iron-coppervein depositsare known there. The Kroumirie-Nefza Zone, which comprisesthe northeasternfrontier regionand the coastalregionfrom Tabarka to Bizerte, is madeup essentially of Oligoceneformations,the lensesor sheetsof "extrusive" Triassic, and the dacite and basalt spursof the Nefza. This zone containsthe main line of deposits:Sidi Driss, Ain Allega, D]ebel Diss, Oued Maden, distributedalong the length of the principal Triassic layer, which takes all the Kroumirie in a slant,from the Mediterraneancoastto the regionof Souk Ahras. This zone comprises the impregnationdepositsand replacements by blende-pyrite-galena. The boundaryof this zone,markedby Triassicsheetsand abnormalcontacts, contains,in its immediatevicinity, the districtsof Bechater,of ztmdouns(Sidi Ahmed,Khanguet,Ben Amara) and of Fedj •Issene. All the rest of folded northern Tunisia representsthe Tunisian Atlas, whichcomprises(1) a northernarea partiallycorresponding to the Tunisian trough,characterized by a thick Cretaceoussequence(6,000 to 12,000m) of bathyalfacies; this is traversedby sheetsor slicesof "extrusive" Triassic, in placescroppingout very extensively;(2) a southeastern part marginal to the Sahel and to the Saharanplatform. The NorthwesternAtlas hasbeensubdivided,somewhatarbitrarily,into: (a) The Sub-Zone of Thrust Sheets (•cailles)/ from Bizerte to the Ouargha,characterized,especiallyin its northeasternsection,by numerous thrust sheets(•cailles) of Eocenelimestones.This showstwo alignments of deposits,having perhapsa commonorigin, toward the Northeastin the vicinity of Mateur, the districtsof E1 Grefa, and Graria, on the edgeof an important Triassic sheet. Toward the Southwest,a first branchcontainsthe z l•caille, literally shell or scale, is here translated as "thrust sheet" for want of a better term. According to Goguel (Trait• de Tectonique), dcaille is used in several senses: an assemblageof folded bedsboundedby a thrust fault; a fragment of a nappe isolatedbetween two other units; a secondarynappe from subdivisionof a major nappe by refolding.--Editor. 160 PAUL SAINFELD deposits of Sidi Bou Krim, Bazina,Tabouna,then,the Djebel Sabbahand the Djebel Bou Sebouaon one side,the Chara, Djebel Hallouf-Sidi Bou AouaneandTouireufon the other;the second comprises the Semene,which 1.ikewise canbe subdivided, onepart with Ain GrichandE1Haouaria,theother partwith Djebba,NebeurandZag andTir. This sub-zone, essentially high in lead,terminates in Tunisiaon the frontier,with the blende-pyrite-galena depositsof Sakiet-Koucha, somewhataberrantmineralogically (the paragenesis is alliedrathermorecloselywith the deposits of the followingsubzone), but in tectonicbearingfrom Touirent. (b) The Sub-Zoneof the Synclinorium, characterized, principallyin the Southwest, by the presence of Cretaceous brachyanticlines and the great Eocenesynclines.It alsocomprises two principalalignments, markedby the Triassicsheets,with a commonorigin towardthe northeast. At the latitude of Medjezel Bab,thealignment E1Alia-Djedaria-E1 Ahmeradividedinto one part with the depositsof Fedj el Adoum,Kebbouch, Dogra, Sidii, Garn Alfaya; the otherpart with thoseof Kef Lasfar, Knana, Koudiat Safra, El Akhouat,Bou Khil, Bou Grine,Lorbeus,Slata,Bou Jaber. This sub-zone comprises replacement depositsas well as impregnation of B.G.P. at the Triassic contact. Towardthe southeast, a strip of nearlybarrencountry,aboutforty km wideextendingfromTunisto Thala,separates the unitsdescribed abovefrom theSouthwestern part of the TunisianAtlas. This region,characterized by Jurassic outcrops, alongthe importantstrikefaults,with impregnations and replacementsof lead or of zinc, has likewise been subdividedinto: (a) The Sub-Zoneof the Za#houan-Kessera Anticlinoriumis well de- finedin thenortheastern part,whereit merges with the Jurassic andAptian massifsof the Tunisiandorsal:Bou Kornine,Ressas,Zaghouan,Djebilet el Kohol,Serdj; there,it dividesintotwo branches: Belouta,Sekarna,Azered, HamraandKef Chambi,separated by a vastsyncline havingon its margin the districtsof Sidi Mabrouk, Ain Khamouda. (b) The Sub-Zone of theFoldsof CentralEasternTunisia,whichbegins at thenorth,ontheflankof thedorsal(HammamJedidi),thenis moreclearly defined at theedgeof theKairouantrench,by thealignment Trozza-LabeiedMhrila-Noubain a southwest direction,and Loridga-Touila-Mezzouna with northerlystrike. (c) To the south,SouthernTunisiacomprises foldstrendingE-W, with the sedimentary deposits of iron and phosphates. Finally, the SaharanPlatform,which occupies all the southernpart of Tunisia, is characterizedby nearly flat Mesozoicformationswith considerable cover. Naturally this undisturbed zone affords few indications of mineralization. Thus, most of the metalliferousdepositsare locatedin the northernpart of the TunisianAtlas. Sinceigneousintrusivesare unexposedin this region, and would be found only at a great depth, this localizationof mineralization is probablyof purely tectonicorigin. StructuralFeatures.--It is in this zonethat the two Atlas chainsof Algeria reunite,after curvingtoward the northeastnear the Algerian-Tunisianborder. , THE LEAD-ZINC-BEARING DEPOSITS OF TUNISIA 161 This curving is especially'markedby two seriesof faults: longitudinalones, which are the more importantbecausethey are commonlythe loci of Triassic "injections," and therefore have penetrateddeeply; the others, transverse, commonlydiminishingto fractures,but perhapshaving reactivatedthe first set in accentuatingthe uplift of the Triassic. The zonesof rich mineralization generally occur at intersections,commonly in associationwith two later systemsof slip fracturesat 45 degreeswith the principaldirections. It is difficultto date thesefaults; the pre-BurdigalianAlpine orogenywas precededby preliminary phases,beforethe Cenomanian,and before and after the Lutetian, and locally there is evidenceof the influenceof thesedifferent phasesin the tectonicsof the region,in particular,the diapirismwas certainly started at the Pyrenian phaseat least. On the other hand, the major paroxysmal phase at the close of the early Quaternary was followed by local subsidence,which still continues. Northern Tunisia has therefore been an area of continuousinstabilitysincethe beginningof Tertiary time. Problem of the Triassic.--The Triassicin North Africa posesa problem that is essentiallystructural. Relationships betweenthe Triassicmaterialand the mineral depositshave long beenrecognized,and it has beenthoughtthat it might have facilitatedthe upward movementof emanations. The Triassic material is literally injected into longitudinalfaults and the successive de- formationsup to the recentparoxysmalphasehaveaccentuated this structure. There is reason to believe that it was then that the mineralization was de- positedat the contactsandin the vicinityof the Triassic,whichit accompanied in its upwardmovement. The Triassiclayersvery probablyrepresenttrue "livingfaults" (36) activefrom Cretaceous up to the presentperiod,and one might imagine that they have maintaineda continuousrelationshipwith the faultsof the basement rocks,the hydrothermal introductions havingbeen derivedfromold mineralization in the basement(6, 15) or evendirectlyfrom deepintrusivemagma. This problemwill be discussed in detail below, but it maybe notedherethat the Triassicinjections andthe hydrothermal introductionswere undoubtedlytwo resultsof the sametectoniccause. Is there entire dependence of mineralizationon extrusivephenomena?One cannot affirmthatthisis soin everycase. It is obviously enticing,in a countrylike Tunisia,whereigneousmagmasare at greatdepth,to substitute for themthis perfectsuccession of the "intrusive"rocksviz., the "injected"sedimentary Triassic. Stratigraphic Distribution The geologicmapof Tunisiashowsthe extentof the Cretaceous, Tertiary andRecentoutcrops. The Jurassicis but little knownexceptin the northern and dorsal massifs,and in somepoints in central Tunisia. The Triassic is almosteverywhere"extrusive"as diapirsin abnormalposition,emphasizing the recentorogeny. If one examinesthe stratigraphicpatternin comparison with the metal- liferousdeposits of NorthAfrica (Fig. 3) onenotesthatin Moroccoonlythe Paleozoicand Liassicformationsare mineralized.Most of the Algerian 162 PAUL SAINFELD depositsare foundin the middleJurassicand the lower Cretaceous, whereas in Tunisiathedeposits areconcentrated in theupperCretaceous andTertiary rocks. One seesa shifting of the mineralizationfrom the Paleozoicto the Mio-Plioceneon passingfrom west to east in North Africa, in accordance with the statistical distribution of outcropsin eachcountry. STRATiGRAPHiCAL DiSTRiBUTiON Of MAiN LEAD -ZINC NORTH MOROCCO •, -- AFRICAN DEPOSITS ALGIERS I--.--=•s•, TUNI$iA I -- I •=•. , r•l•., I -- I ( 11•estone• ann I'• 8ffi •0• NummulKic (•rl, aria limestones) • O• I •;•o•i• •NG• (l•mestones and I , •0• •o• • o= •KZ• - KO• G•G0• C•nomani• I (Albo-Ap•i•n lime, cones and •LO• I• •O J•B• •. (limestones * I (brec•a) BOU I'AOUZ Fro. 3. THE LEAD-ZINC-BEARING DEPOSITS OF TUNISIA 163 Althoughthe controlof mineralization by physicallyfavorablerocks,such as'disturbedmicro-brecciated bedsor chemicallyfavorablerockssucha• limestonesand dolomites,is strictly applicablein Moroccoand the greater ' part of Algeria, certainexceptionsto it can be found in Tunisia. The Permian cropsout only in the Sahara, in the small anticlinalrange of Tebaga, where it consistsof fractured dolomitesand limestones,with a small zinc-bearingvein deposit. In northernTunisiathe Triassicis almostexclusively"injections"through the overlyingformationsalongfaults, especiallystrike faults. It commonly consistsof a bi-coloredargillo-gypsiferous brecciacontainingblocksof dolomite and sandstone.It is itselfrarely mineralizedbecause of its impermeable naturebut,.quite anomalously, sandyclaysand especiallycertaindolomitic bars or breccias,particularlyimportantin the al10chthonous brecciaand always closeto the contact,carry workablestockworksand replacements (Ain Allega,Bazina,Bechater,S.idii,Dogra,Zag and-Tir, Loridga); the extension of suchdeposits, is alwayslimited. But the marginsof the lensesof Triassic at their contacts with highlycontrasting formations commonly carry an autochthonousfriction brecciacontainingenrichedzones.that are commonly lenticularand are locallycalled"contactdeposits"(g•tesde contact). Most of the B.G.P. deposits of the southernpart of the TunisianAtlas belongto this type,-commonly associated with depositsin transverse veins (SakietKoucha,Fedj el Adourn,Kebbouch,Garn Alfaya, Kef Lasfar, Knana, E1 Akhouat,'BouGrine,Lorbeus). Jurassicformations rarelyoutcropexceptin the northernendof the axial anticlinorium of the TunisianAtlas; they are composed of hard limestones, eitherLiassic(Grand Zaghouan,Djebilet el Kohol) or Portlandlimestone (Ressas,Sidi et Taia, HammamZriba), very favorable to lead-zincreplacement deposits. The Neocomian, essentially marty,is rarelymineralized.It is, however, in limestones of lowerCretaceous agethat the petroleum well drillednearE1 Akhouat,has cut, at 2685 m, a stockworkof sphalerite,calciteand galena. It is the samewith the bathyalAptJanof the Tunisiantrench,but toward the south,this formationbecomes favorableto replacement depositseither in the sub-zoneof the synclinorium(hard limestones of Slataandof Bou Jaber), or in the anticlinoriumand in centralTunisia (limestonesand dolomitesof Serdj, of the Azered,of the Hamra, Kef Chambi,Trozza, Ain Nouba and of Touila). The Cenomano-Turonian, very marly in the north, containsthe curious impregnationdepositof the Djebel Diss. It is morecalcarious in the northern part of the Tunisian Atlas, and containsseveralvein depositsand stockworks associated with the "contactdeposits"(Fedj Asserie,Djebba, Nebeur, Fedj el Adoum,Garn Alfaya, E1 Akhouat); towardthe south,it becomes dolomitic, with' replacemeht deposits(Kef Chambi). The smallmanganese depositsof southern Tunisia also occur in this formation. The Lower Senonianis alwaysmarly, and only the impregnationdeposit of Oued Maden in Kroumirie is known there. The.Upper Senonianshowsmany vein deposits(with cavity fillings) in 164 PAUL SAINFELD THE LEAD-ZINC-BEARING DEPOSITS OF TUNISIA 165 its upperpart whichconsists of the ratherhard massivelimestones of the Maestrichian in all the northern zone of the Tunisian Atlas (Andouns, Tabouna, Chara, Hallouf, Sakiet, Lorbeus). The Eocenecontains,in its middlepart, the massivelimestoneswhich, althoughof favorableappearance, are rarely mineralized(Touireuf, Sekarna). However, the baseof this seriescontainsall the thick sedimentarydeposits of iron (Djebel Anh) and of phosphate. Depositsin the Oligoceneof the Kroumirie-Nefzazoneare unknown;in the Tunisian Atlas this formationcontainsthe small replacementdeposits of KoudiatSafraandof Djebelel Abeid. The sandstones of the Burdigalian containseveralsmallreplacement deposits in the northernpart of the Tunisian Atlas (El Alia, Diedaria, E1 Haouaria). Finally, the Mioceneat the north of the samezone containssmall replace- ment depositsand relativelyimportantinterstitialimpregnation, (Djalta, Semene,Sidi bouAouane). It appears,then, that there is a distributionof mineralizationthroughout the whole stratigraphiccolumnof Tunisia; the principal depositsare im- pregnations at the "Triassiccontact,"replacement deposits in the Jurassic, the Aptian andthe Miocene,andvein depositsin the upperCretaceous, as well as the cavityfillingsassociated with all thesetypes. Despitethis distribution, all thehydrot•hermal deposits areprobably of thesameage. CHARACTER OF'..DEPOSITS Types of Deposits Replacement depositsproper occurmainly in the limestones-and sandy conglomerates in the smallMiocenesynclinesof Bejaoua(Djeb•l- d -Grefa, Djebel Semene,Sidi bou Aouane) where the ore is very fine-grainedand almostentirely of lead (Figs. 4.1, 4.2 and 4.3). A more classictype of replacement with largecrystalsoccursin association with otherkindsof depositsin Aptian limestones and dolomiticlimestones towardthe southeastern FxG. 4. Aa Various recent cover (crusts, scree,soils). pq Early Quaternaryand Pliocene(lacustrinebrecciatedlimestones). m• Mio-Pliocene(clays and hostseriesof sandstone, conglomerate and lacustrine limestones). exv-Cø Marls at the transition from Cretaceousto Tertiary. c• Upper Senonian(host rock series of.massivelimestones,with marly and marl-lime intercalations). c7 Lower Senonian(marls with somelimestoneintercalations). c•q• Aptianhostrock(alternations of limestones), qu'•rtzites /•d marls,with massive subreef limestone). C•v-v Neocomian(marls and marly limestones ). js-, Portlandianhost rock (.massivesubreeflimestone). t Triassicdiapir and extrusive (gypso-dolomiticbreccias) Black = mineralized zones. (e = Pb; B.P.G. = Blende, Pyrite, Galena) Vertical scale equalshorizontal, shown at the side. 166 Pat UL S•tlNFELD - .. '• . '%3' '• . -• • •z-. :...• .. : :• ..:. :'•:f•.. •7• *',•.."*:."'; i C ii i r r .. r ,it r r r , , , rr :.:.;% ß ...-. .:.:. ß .'-' ';5' •'•, ' 4...•.... "•.:.':' .. 7,::./?..' .•- ....:..":*i' '*• ,, ,, ., ,- ..... ' ..'•.... ?:::;'::'- " .: . . • • •. . *•'-.* :.... -.;:.;.:. .3 . THE LEAD-ZINC-BEARING DEPOSITS OF TUNISIA 167 end of the TunisianAtlas. Zonesof veinsmayoccuralongwith replacements as at Djebel Slata (Fig. 4.5) but a rather commonoccurrenceis galenain caves, ßpipes, or rugs of karst origin, indicatingthat the mineralizationwas later '-::than oneor moreemergences. Somenodules of massive galenaweighing up to 40 kg (Fig. 6.1) are moldedin karst cavities(Djebel el Hamra). Certain beds (Slata) or walls of cavitiesare lined with galenacrystals,someof themenormous(Fig. 6.2). One cavity,at Sidi Bou Aouane,yieldedbeautiful stalactites showingin crosssectionone or two concentric rings of galena in calcite(Fig. 6.3). Simplevein depositsare not very commonbut clean-cutveinsare known in the Senonianlimestones, as at Fedj Assene,wherethe mineralization is largelyblende,and at Djebel Hallour (Fig. 4.3), whereit is of lead-arsenic and highly oxidized. But the beautifulclassicB.P.G. lodes,concretionary and crustified,well knownin the limestones of the upperCretaceous of the Kef region(Fig. 6.5), are associated with the impregnations alongfissures at the Triassiccontact(Fedj el Adourn,Djebel el Akhouat,Sakiet-Koucha) (Fig. 4.4). The type intermediate betweenveinsand replacement depositsis well represented in North Africa: this is the fissuredeposit(#•te de cassure)of the Moroccan geologist (7). Its aspect is vein-likewith brecciafillings,but thereis alsoreplacement or impregnation of the lodewalls,as well as filling of the cavitiesin the vicinityof the fracture;thismixedtypeis common in the Senonian limestones (Amdouns). Finally,a fourthtypeof depositpeculiarto Tunisiaandto the Constantine consists of fissure impregnation; it is nota truereplacement buta filling,by way of very fine stockwork,of thin fissuresof millimetersize, without preferredorientationin the varioustectonicbreccias,either in the broken zonesat thecontact of theTrias (commonly witha vein-likeextension), or in broken thrustplates ofEocene (Ressas-Touireuf) or Jurassic (DjebelRessas) limestones (Figs.4.6 and5.6). Theseimpregnation deposits, aswellascertainveins,maycontain lenticu- lar zones of enrichment (the"colonnes" oftheminers),generally at theinterFxc. 5. Replacementdeposits. 1. ContinentalMioceneof the Djebel Semene.--Redconglomerates, with idiomorphicand aciculargalena (white), arounda limestonepebble:Reflectedlight. X 150. 2. Oligoceneof KoudiatSafra.--Sandstone with bandsof galena,preferentially in lignitic partings. X 4/5. 3. Cenomanianof the Kef Chambi.--Dolomiticlimestonewith runs of galena. X 1/3. 4. Aptian of the Djebel bou Jaber.•Limestone with crystalsof galena in the ground mass. 5. Aptian of Sidi Amor ben Salem.•Dolomitic limestonewith galena and baguettesof quartz showing rhombohedralforms of the carbonates. Polarized light. X 140. 6. Depositsof impregnationof disturbedzones. Jurassicof the Djebel Ressas. mBreccia fragments of white calcite in large granules, and fine cementof black calcite, galena and sphalerite. X 2/3. 168 ?.-• UL S,4IA?FELD ,.. .•. .:. *; ;'4i .... ,•,-•' b-c , :" .:¾'•. ai;,•4:..,-,.'-.. ': .., .:...;:.':;.-:" '{; •,.7' ";;? "ic,-.f•**' 4 FIG. 6. ....*:'..?::*k•; •i•/' :8:'.:' THE LEAD-ZINC-BEARING DEPOSITS OF TUNISIA 169 sectionof faults, veins or fractures. It is possiblethat these openingsare at least partly of karst origin. Oxidation In certain Tunisian deposits,gossansare mostly absent,except for the outcropsof certainveinswhere they are alwaysferro-calamines, with galena boxworks,as at Djebel Hallour and at Sakiet. Nevertheless,oxidizedzones are generally very important in a limestoneenvironment. They are composedessentiallyof carbonates--smithsonite (with hydrozinciteand calamine) andcerusite(with anglesiteand residuesof galena). No zoneof cementation is recognizedin the Tunisiandeposits. The limit of the oxidizedzoneis, generally,aboutthe groundwatertable. However,in a marly environment the oxidationis generallyvery superficial, and the sulphidezone in blende-pyrite-galena or in blende-galena extends almost to the outcrops (Oued Maden). There are, however, several lead depositswith deepoxidation,at the edgesof collapsestructures,in particular of that of the Medjerda (Djebel Hallour and Touireuf). Here the oxidized zonereaches at leastto a hundredmetersbelowthe presentgroundwater table. This is the caseonly in a limestoneenvironment;at the flank of Djebel Hallour, the depositof Sidi Bou Aouane,with marly walls is practically withoutan oxidizedzone (Fig. 4.3). Tectonic Distribution It is interestingto note that to someextent the mineralogicdistribution follows the tectonic lines. The Kroumirie-Nefzazone containsthe B.P.G. and B.G. deposits,with very fine crystallizationonly slightly oxidized, with mercury, arsenicand antimony. The margin containsfew deposits,except lead and zinc, and little iron; theseare in all casesstronglyoxidized. In the Tunisian Atlas, the sub-zoneof Bdjaoua-Ouargha is almostexclusivelylead-bearing(at least, at the presentstageof depth exploration). The synclinoriumcontainsB.P.G. depositsof rather coarsecrystallization. Finally, the anticlinoriumand centralTunisiagenerallycarry simpledeposits, FxG. 6. Deposits of solution cavities. 1. Aptian, Djebel el Hamra.--Kidney of galena, encrustedwith cerusite,showing forms characteristicof karst cavity. X 1/8. 2. Aptian, Djebel Azered.--Group of galena cubes,ericrustedwith calcite, in the wall of a cave in Aptian limestones. X 1/5. 3. Miocene of Sidi bou Aouane.--Stalactite of calcite (seen in section), with two concentricrings of galena (solution channel in lacustrine limestone). X 2. Veins 4. Eocene, Ragoubet Halgen Naga.--Vein of calcite with pisolites of galena, aragonite and sphalerite. X 1. 5. Senonian,Sakiet Sidi Youssef.--Concretionin cockadeof sphalerite(schalen• blend) with crystals of galena 'in somebands. Recurrence of the two minerals around a fragment of limestone. X 1. 170 P/IUL SAINFELD whether lead ores or zinc ores. SouthernTunisia is characterizedby sedimentary deposits(iron and phosphate). It is unlikely, in so far as the hydrothermaldepositsare concerned,that this distribution indicatesdifferent cycles of deposition. In Tunisia the associationis in all caseslead-zinc-iron although one or the other of the elementsmay be dominant. Characterof Ores MajorElements.--The Fe-Pb-Zn association is represented on theone hand by depositsalmostexclusivelyiron-bearing;on the other, by lead-zincbearingdeposits,in most of which lead or zinc dominateover other metals. Iron is still presentin proportionequalto or evengreaterthan the two other constituents,in somecappingsand sulphidezonesof depositswith B.P.G. TABLE AN•.L¾S•-S Deposit ..... i El Grefa Marketable ore Pb 61.07 Zn 1.64 Ag (per ton) ' III OF OR•-S BouAouane Sorted ore 67 5.10 4 gr SidiAmor Dj. Hallour Sakiet Sorted ore High grade ore Coarse ore 62.25 22.06 3.78 0.10 2.84 5.68 5.60 400 gr Fe20• 2.78 6.84 1.21 5.91 As $b 0.33 0.20 2.95 1.62 0.01 0.10 0.61 0.05 S 9.89 17.25 7.02 SiO2 0.80 0.72 8.25 0.68 7.48 1 !.80 1.40 0.40 22.23 20.00 Alg)• . 2.52 6.31 12.87 21.90 CaO 4.50 MgO 0.11 0.10 0.26 0.36 3.48 10.90 3.44 5.76 1.88 22.68 16.15 $O•Ba, $r C02, 0 ,, paragenesis, whichrepresenta little lessthana fourthof the lead-zinc-bearing deposits--some 12 or 13 deposits,locatedentirelyin the synclinoriumof the Tunisian Atlas. This paragenesisin the districtsof Fedj el Adourn and of Djebel el Akhouat has been the subjectof a detailedmineralogicalstudy by J. Bolze and I-I. Schneiderhohn (6) from which the followingpassages are taken: "The Blende . . . of the schalenblende type . . . in all casesshowsbeautiful concretionarystructures,in cockades... the colloidaltexture shows a mosaicof veryfinelamellaeof twinnedsphalerite .... Thereis no indication of a changefrom the colloidaldepositof Zn to the stateof schalenblende by way of wurtzite." But, in the Algerian'andTunisiandeposits, the blendeis commonlycompletelyoxidized,and the ore is composed of smithsonite, in someplacesac- Companied by hydrozincite and hemimorphite; theseare the calamines of miners,whichappearin very diverseforms. They are rarely crystallized, generally massive, banded, mammillary or concretionary or stalactitic in shape, and of a great variety of colors. THE LEAD ZINC-BEARING DEPOSITS OF TUNISIA 171 "Galena is generally well crystallizedin simple cubic forms.... The crystalsare often deformedor even crushed." In the oxidized zones,the lead appearschieflyin the form of black cerussite,very finely crystallized. "The sulfideof iron is deposited principallyas marcasite. . . in beautiful concretionary or arborescent forms.... Pyrite generallyformsthe baseof simpleradiatingcrystalsof marcasite. Finally, an amorphous or crystalline sulphideof iron in the form of melnikovit-pyrite sometimes is visiblein small spherulites .... The sequence of the three sulfidesis not constant. Nevertheless,in general the following succession is observed:galena, blende, marcasite-pyrite,calcite." At Sakiet Sidi Youssefan identicalassociation showsa first deposition of galenaandquartz,with secondary calcite,anda second deposition of pyrite, blende, marcasite andschalenblende (in places replacing thepyrite),thewhole accompanied by latercalciteand quartz. On the otherhand,in anothervein, the succession is normal: schalenblende, then galena. In additionthere are recurrences of the threesulphides providingbeautifulbandedspecimens (Fig. 6.5). In the B.G. deposits,a reversalis alsocommon;the pisoliticoresof RagoubetHalgenNaga show,at the centerof the pisolites, corrodedcrystals of galena,concentrically coatedby calcite,jordanitcand blende(Fig. 6.4). It appearsimpossible,in Tunisia, to use the texture of the ore and of galenain particular,in determiningthe age or the type of deposit. The texture seemsto dependsolelyon the environment;the grain size of galena is very fine in a marly environment(in the.replacement depositsof the MioPliocene,in someveinsor disseminated deposits),but the grain of the galena becomescoarserin a calcareous or dolomiticenvironment(in the vein deposits,the impregnations at the Triassiccontactand the replacementdeposits in the Cretaceous). The fineness of grain of the galenaandof the cerussite is extraordinaryin someTunisian deposits,ranging about a micron and suggestingdepositionas a colloidalgel. Minor Elements.--It has not been possibleto establishthe relation between the silver contentof the lead ores and the type of depositor its relative age. The Tunisian.ores are sparselysilver-bearingon the whole--the depositsof impregnationand of replacementin the Portland and AptJan limestones seemto havethe highestcontent,quiteregularlyfrom 250 to 500 gramsper ton. The replacementdepositsin the Mioceneare not silverbearing. Betweentheselimits,the silvercontentdoesnot seemto obeyany law. The otherelementsare lesswidelydistributed,and still lesswell known. Cadmium,in the form of greenockite, has beenrecognized only in some B.P.G. deposits of the subzone of domes,in the regionof Kef (Fedj el Adoum, Sakiet-Koucha, Garn Alfaya). Vanadiumis knownin the fissuredeposits of Djebba,of OuedKohol and of Hamman Jedidi (vanadiniteand dechenite),the replacementdepositsof the Djebel Agab (vanadiniteand descloizite)and the impregnations of Ain Allega and of the Djebel Diss (vanadinite). Molybdenumhas beenfoundsporadically in the impregnationdepositsof Touireuf, in the form of wulfenite. 172 PAUL SAINFELD Mercury is found in small quantitiesat Oued Maden in the form of cinnabar and metacinnabarand alsoat Djebel Arja (cinabre). Arsenicis presentin someof the deposits at the boundaryof the Medjerda trench in the form of realgar (Oued Maden, Fedj Assene), mimetite and jordanite (Djebei Hallour, Sidi bou Aouane). Antimony is alsoquite uniformin the depositof Oued Maden in the form of stibnite and boulangdrite. Copperis very widespreadin mostof the metalliferousdeposits,generally in small quantities(berthoniteat Slata, bournoniteand tetrahedriteat Oued Maden,chalcocite at the Kebbouch,chalcopyrite, azuriteand malachitein the iron gossans). Manganeseis rather rare in the lead-zinc-bearingdepositsin the form of cesarolite(Slata, bou Jaber). Thus all the minor elementsare sporadicand unimportant. Gan#ueand AccessoryMinerals.--The gangueof the ores is generally limestone,calcitic,dolomiticand iimonitic,rarely argillaceous or gypsiferous; barite appearsquite commonly,especiallyin the upper zonesof the deposits; fluorite and celestiteare presentin a few deposits. Nevertheless,thesethree mineralsservein placesto form smallworkabledeposits. Hydrothermalsilica is rather rare; quartz is present,however,in some vein depositsor B.P.G. replacementdepositsat the contact of the Triassic. But the Aptian formationsof the Cretaceousarchesare commonlysilicified; one seesthere a veritable invasionof the limestonesby rods and needlesof quartz, forming rocks of lattice structure of an extraordinary toughness (Fig. 5.5). The samephenomenon is foundin someJurassiclimestonesand dolomiticlimestonesof the dorsal. This silicificationin many casesseems to be precededby dolomitization,perhapshydrothermalalso, and both phenomena antedate the advent of the lead-zinc. Origin of the Hydrothermal Solutions Tunisia is a perfect illustration of the problem of telethermaldeposits, remote from any eruptive magma; the sedimentarycolumn is very thick. The only outcropsof igneousrocksare found at about60 km off the Tunisian coast in the archipelagoof la Galite, consistingof granular (granodiorites) and micro-granular (microgranites) rocks, with only a few iron-copperbearingveinlets;and in the Nefza, where there are someflows of daciticand basalticrocks. The greaterpart and the most importantof the metalliferous depositsare locatedin the southand even there the only igneousrocks are someblocksof ophiteembedded here and there in the Triassicand they do not play any metallogenicrole. We have examined,above,the tectonicproblemposedby the Triassic and have shown how various authors have interpreted it as intrusional, intermediate in nature between magma and sediment, or a companion or source of ascendingthermo-mineralemanations. This associationis well illustrated in the Tunisian Atlas; it has been establishedthat there is particularlybetweenthe two mineralizedregionsof the synclinorium and the THE LEAD-ZINC-BEARING DEPOSITS OF TUNISIA 173 anticlinorium, a hiatusforminga sterilezoneabout40 km wide,whichis very undisturbed,and almost devoid of Triassic outcrops. The mechanical roleof the Triassic,unquestionable as far as the movement on the "living faults"is concerned, woulddoubleas a chemicalrole: the "primitive"deposits, whetherin the Triassicor Liassic(15), or in the basement faults (6), wouldhavebeendissolved and their elementsretransportedby waterschargedwith salinesolutions in their movement to the contactof the Triassic. We have seen that most of the depositsof the Triassiccontactin Tunisia showa commonreversalin the B.P.G. paragenesis; sulfuretted hydrogelof leadandzincwouldhavedeposited firstleadsulphide, thenblende,with a colloidaltexturein rosettesaroundcrystalsof galena(6). In brief, the Tunisiantelethermaldepositswouldbe the "emigrantdeposits" (L. Glangeaud)or "secondary hydrothermals" (H. Schneiderhbhn). This hypothesis, however,calls for the followingobservations: (1) Morethanhalfof theminingdistricts arelocated at a certaindistance (1 km or more)fromtheTriassicoutcrops, commonly withthickimpermeable formations between them. (2) The principalTriassicmassifs(Oued Zarga, Debadib)are not associatedwith importantdepositsin the area. '(3) We know of no importantmineralization within the Triassicand haveno recordin fragments of the Triassicbreccias of a formermineralization. On the other hand there may be present,especiallyat the borders of theophiteblocks,suchmineralsastourmaline,actinolite,hematite,epidote, andpyrite,representing a belatedhydrothermal pneumatolytic phase. Why should not the arrival of Fe-Ph-Zn be another manifestation of the same kind? (4) Chemical considerations (reversalor absence of silica),applyto only a part of the Tunisiandeposits.Furthermoreabsence of silicais far from absolute;quartzis presentin someB.P.G., and especially in mostof the deposits locatedin the Aptianformations, wherean importantsilicification is associated with the dolomitization. These latter characteristics recall the great American replacementdeposits. (5) Finally,if onestresses, in a generalway,andwith goodreason,the telethermalnatureof the Tunisiandeposits, it is still no lesstrue that there was eruptiveactivityduringthe courseof the Miocene;and this, though evidentlyvery local,mustnevertheless havepreceded the metalliferous emplacements. In summary, whilethistheorycanaccount for a certainnumberof impregnations of B.P.G. of the TunisianAtlas, it appearssomewhat premature to extend it to all of the North African deposits. Moreover,certainhot springsthat rise in the vicinityof somedeposits havealsobeenexamined,aswell asall the waterspumpedout of the principal mines. TheTunisianthermalsprings are,onthewhole,chlorinated, sulfated, or chlorosulfated, and few are knownnear the deposits;the main onesare thoseof HammanGabrit,nearthe KharguetKef Tout (26ø), HammanLif, at thefootof DjebelbouKornine(43ø and50ø), HammanJedidi(61ø), HammanZriba (46ø) andHammanZebbeus, at the footof Kef Chambi 174 PAUL $AINFELD (35ø). But the relativelydeepworkingsof somemineshave tappedhot waters:Djebel Hallouf, at 175 m in depth (29ø); $akiet $idi Youssef,at 150m (23ø); $idi Amor ben Salem,at 220 m (38 to 42ø); Bou Jaber-Est, at 50 m (38ø). Yet the low leadcontent(lessthena milligramper litre) of certainhot or cold waterspumpedfrom minesdoesnot seemto bear any relationto their temperature. Thus, the water of $idi Amor containsonly 0.15 mg of leadper liter,.whereas the coldwatersof Fedji el Adoumcontain from 0.4 to 0.8. There must be, in certain cases,a mild dissolutionof the sulphates or carbonates of leadof the deposits, andthereis no reasonto think thatthehotwatersrepresent theresidues of themineralizing solutions. Age of Minerali, ation To resolvethis problem,there are availablethe lesstheoreticalfactors. It has beenseenthat the first knownphasesof Triassic"injection"date, at least,from the Pyrenneanmovements, at the beginningof the Tertiary; but it seemsindeedthat the Triassicwas not then accompanied by mineralizers. No indicationshave yet beenfound in the pebblesof the conglomerates of the lower Miocene. The replacement depositsin the Mioceneof Northern Tunisia give us, moreover,a preciseindication,for we have shownthat there is no compellingreasonto postulatemanycyclesof deposition, but ratherseveralstages in the samecycle(variationsin the B.P.G. paragenesis, brecciasrecemented by ore). In particular,examination of the depositof Douaria(17) shows that the ferriferous mineralizationthat affects the continentalbeds whosetop is well datedas Pontian,wasprobablycomplete at the endof this epoch;one finds,indeed,in the overlyingnon-mineralized beds,pebblesof ore derived no doubtfrom the mineralizedbeds,for it appearsdifficultto imaginethat thesewould have beenmineralizedafter their deposition. One is therefore ledto conclude that theTunisianore deposits are relatedto the lastparoxysmal phaseof the Alpinefolding,that is to say,they are of Mioceneage. Indeed,a final indicationis affordedby a deepoxidizedzonein certain leaddeposits at the edgeof the subsidence trenchof the Medjerda(Djebel HalloufandTouireuf). Onecanhardlyexplainthisphenomenon exceptby the existence of a fossil water table which would be related to the amount and rate of subsidence.Therefore,the ores must have beendepositedprior to theisostatic readjustment thathascaused diverselocaltrenches of subsidencein Tunisiathroughout the recentQuaternary. Thesefinalmovements areagainattested bydistortion, crushing andevencuttingof mineralization by the later Triassic"injection,"and even by small faults of readjustment, subsequentto the mineralization. CONCLUSIONS: CONDITIONS OF DEPOSITION Thegeneral geologic andmetallogenic considerations permitusto examine thefactorscontrolling the localization of the lead-zinc oresin Tunisia? z The percentages are calculatedaccordingto the importance of the deposits(tonnage taken out and reserves at the close of 1953). THE LEAD-ZINC-BEARING DEPOSITS OF TUNISI./I 175 (1) The structural factors seem the most important: the metalliferous depositsare concentrated in the foldedarea of Tunisia, that is to say, at the border of the Alpine zone, and particularlyin the northwesthalf of this region (75 percentof the deposits). There is a quasi-periodic distributionof the principaldistricts,followingthe tectonicalignments. The B.P.G. paragenesisis certainly related to the last Alpine phase. A statisticalanalysis of the relationsbetweenthe visible faults and the mineralizationgives the followingresults: strike faults (with or without intruded Triassic) appear in almostall cases(85%), associatedwith the transversefaults (13%) or with slips (fracturesde glissement)(9%) or, particularly,with one or the other (50%). (2) The stratigraphic factorsdependon the physical-chemical conditions. In the absence of igneousrocks,onenotesa distributionof the mineralizatiofi in all the Mesozoicand Tertiary sectionor in companywith the layersof the "extrusive" Triassic. The statisticalanalysisshowsthat there is a direct relationbetweenthe favoredstratigraphicstagesand the nature of the rocks that composethem: the upper Cretaceous, calcareous,containing38 percent of the known ore deposits,the middle Cretaceous,calcareousand dolomitic, 17 percent,the Jurassic,calcareous, 15 percent(althoughnot very extensive); the Neogene,conglomeritic sandstone 13 percent,the Triassicandits brecciated border,12 percent,and finallythe Paleogene, calcareous and sandy,5 percent. (3) The physical-chemical conditionsare naturally in accord with the precedingfactors:the "extrusive"Triassicor diapir probablyplaysa double mechanicaland chemicalrole, and, if its influenceon the hydrothermalactivity is not demonstrated in all cases,.it is very probablefor one part, at least, of the lead-zinfibearingdeposits.The mineralization in Tunisiais not entirely localizedin favorablerocks,that is to say, in readily faulted horizons, in shatteredzones with micro-fracturedconstituents,and especiallyrocks subjectto easyand large scalesolutionand metasomatism (78% of the instances). If the limestones,in fact, representthe principal host (52%), next the dolomites(11%), the brecciasof the Triassiccontact(8%) and the sandstones and conglomerates (7%), it is none the lesstrue that there are substantialimpregnations in suchrocksas the marls or the clays. This fact is quite characteristic, as well as the relativebarrennessof the dolomites,as comparedto Morocco,for example. The relativeimportanceof the typesof depositsis not easyto determine, because of their complexity. At mostonecansaythat the vein deposits, with impregnationof lode walls and filling of cavities,exceedthe depositsof impregnationand of true replacement. (4) Tunisia forms, with the Constantine,a Mediterraneanmetallogenic sub-province characterized by the uniquelead-zinc-ironparagenesis.Despite local variationsin the predominanceof one or another of theseelements,one can considerthat there was only one period of mineralizationwhich was quite recent,of Mioceneage. (5) The fineness of the grain,the concretionary and ribbonedappearance of the ores,in placespisoliticor stalactitic,indicatesdeposition at low tempera- 176 PAUL SAINFELD ture (on the orderof 100ø). The almostcompleteabsence of eruptiverocks makesTunisia a type countryof telethermaldeposits. DIRECTION DESTRAVAUX PUBLICS, TUNIS• October 12, 1955 REFERENCES 1. Archives In•dites de la Direction des Travaux Publics de Tunisie. 2. 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